Five-time champion and second seed Venus Williams lost 2-6, 3-6 to Bulgaria's Tsvetana Pironkova in the quarter-finals of Wimbledon on Tuesday.
Williams, whose loss meant she failed to reach the final for the first time since 2006, was outplayed from the outset by the world number 82 on Court One at the All England Club.
Pironkova, the lowest ranked player left in the women's draw, will play either Belgium's Kim Clijsters or Russian Vera Zvonareva for a place in Saturday's final.
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